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31.
Xianzhong Cheng Kun Shao Shangyue Shen Shenghong Hu Haiou Qiu 《Geostandards and Geoanalytical Research》2011,35(4):461-469
A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l?1 HNO3. The sample solution in 0.4 mol l?1 HNO3 was pumped through an ESM microcolumn at the rate of 1.0 ml min?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values. 相似文献
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广西合浦、南宁、宁明、百色盆地烃源岩有机地球化学特征与勘探潜力分析 总被引:2,自引:1,他引:1
广西合浦、南宁、宁明等第三系盆地的主要烃源岩层与百色盆地一样,均是中始新统深湖-半深湖相暗色泥质岩层,特点是分布面积广,厚度大,有机质丰度高.有机碳含量多数大于2.0%,达到"好"到"最好"的评价标准.有机质成熟度多数处于低熟阶段,部分在成熟阶段.干酪根类型主要为Ⅱ1型.综合分析认为:合浦、南宁、宁明三个盆地都具有优质... 相似文献
34.
滇东地区煤田构造格局与煤系赋存规律的研究 总被引:1,自引:0,他引:1
滇东地区位于特提斯和环太平洋构造体系的交接部位,煤田构造格局的总体特征是呈NNE向条带状展布。区内断层以NNE、NE向为主,受主要断裂影响,煤田在南北向呈带状,东西向呈段状展布,各煤矿区在平面上呈NE向带状分布。研究区煤系赋存受基底主干断裂的控制作用明显,变形强度由北向南逐渐增强,北部地区以褶皱构造为主,断层较少,煤层多保存于向斜构造中,保存较完整,煤层埋藏较深;南部受弥勒-师宗断裂带影响,断裂构造极为发育,对煤层破坏严重,煤系赋存不稳定。 相似文献
35.
Fan Yang Guangxin Zhang Xiongrui Yin Zhijun Liu Zhigang Huang 《Environmental Earth Sciences》2011,64(8):2119-2126
The objective of this study was to develop an empirical equation for estimating the capillary rise in the saline-sodic soil
area of Songnen Plain in China based on the Averianov formula. The capillary rise was observed under five controlled groundwater
levels by lysimeters. Field experiment results indicated that capillary rise had close relationship with the groundwater table
depth, soil moisture of 10–40 cm soil layer and leaf area index. These factors have been taken into account to develop the
empirical equation for capillary rise simulation. The model parameters for Songnen Plain were derived by Levenberg–Marquardt
and global optimization calculating method. The modeled capillary rise has a good agreement with the observed data (r
2 = 0.875). With the simulation model, the critical water table depth was identified as 2.5 m, indicating that soil secondary
salinization will not occur when the water table depth is deeper than 2.5 m. Therefore, in the irrigation areas, groundwater
table depth should be controlled to be higher than 2.5 m to prevent the occurrence of soil secondary salinization. The results
from this research will provide useful information for the water sources management and soil secondary salinization control
in Songnen Plain of China, one of the most serious saline-affected areas in the world. 相似文献
36.
A spectral mixture model analysis of the Kuroshio variability and the water exchange between the Kuroshio and the East China Sea 总被引:1,自引:0,他引:1
For understanding more about the water exchange between the Kuroshio and the East China Sea,We studied the variability of the Kuroshio in the East China Sea(ECS) in the period of 1991 to 2008 using a three-dimensional circulation model,and calculated Kuroshio onshore volume transport in the ECS at the minimum of 0.48 Sv(1 Sv ;106 m3/s) in summer and the maximum of 1.69 Sv in winter.Based on the data of WOA05 and NCEP,The modeled result indicates that the Kuroshio transport east of Taiwan Island decreased since 2000.Lateral movements tended to be stronger at two ends of the Kuroshio in the ECS than that of the middle segment.In addition,we applied a spectral mixture model(SMM) to determine the exchange zone between the Kuroshio and the shelf water of the ECS.The result reveals a significantly negative correlation(coefficient of-0.78) between the area of exchange zone and the Kuroshio onshore transport at 200 m isobath in the ECS.This conclusion brings a new view for the water exchange between the Kuroshio and the East China Sea.Additional to annual and semi-annual signals,intra-seasonal signal of probably the Pacific origin may trigger the events of Kuroshio intrusion and exchange in the ECS. 相似文献
37.
Effect of reclamation time and land use on soil properties in Changjiang River Estuary,China 总被引:4,自引:1,他引:3
ülo MANDER 《中国地理科学(英文版)》2011,21(4):403-416
The objective of this study is to analyze soil physical and chemical properties,soil comprehensive functions and impact factors after different years of reclamation.Based on the survey data taken from 216 soil sampling points in the Fengxian Reclamation Area of the Changjiang (Yangtze) River Estuary,China in April 2009 and remotely sensed TM data in 2006,while by virtue of multivariate analysis of variance (MANOVA),geo-statistical analysis (GA),prin-cipal component analysis (PCA) and canonical correspondence analysis (CCA),it was concluded that:1) With the in-crease in reclamation time,soil moisture,soil salinity,soil electric conductivity and soil particle size tended to decline,yet soil organic matter tended to increase.Soil available phosphorous tended to increase in the early reclamation period,yet it tended to decline after about 49 years of reclamation.Soil nitrate nitrogen,soil ammonia nitrogen and pH changed slightly in different reclamation years.Soil physical and chemical properties reached a steady state after about 30 years of reclamation.2) According to the results of PCA analysis,the weighted value (0.97 in total) that represents soil nutrient factors (soil nitrate nitrogen,soil organic matter,soil available phosphorous,soil ammonia nitrogen,pH and soil particle size) were higher than the weighted value (0.48 in total) of soil limiting factors (soil salinity,soil elec-tric conductivity and soil moisture).The higher the F value is,the better the soil quality is.3) Different land use types play different roles in the soil function maturity process,with farmlands providing the best contribution.4) Soil physi-cal and chemical properties in the reclamation area were mainly influenced by reclamation time,and then by land use types.The correlation (0.1905) of the composite index of soil function (F) with reclamation time was greater than that with land use types (-0.1161). 相似文献
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An abrupt ice and snow storm disaster which occurred in the spring of 2008 se-verely destroyed forests over a surprisingly large portion of southern China.A transect crossing Jinggang Mountain-Jitai Basin-Yushan Mountain-Wuyi Mountain was selected as the study area.The authors integrated field data collected in two field surveys to analyze the impacts of the disturbance on forests.The following results were obtained.(1) The extent of damage to plantations along the transect decreased in the order of slash pine > masson pine > mixed plantation > Chinese fir.Slash pine is an introduced species from southern America which is characterized by fast growth,low wood quality and rich oleoresin,and showed a damage rate of 61.3% of samples,of which 70.4% cannot recover naturally.Masson pine is the native pioneer species of forests with harder wood,and 52.5% were damaged due to turpentine,of which 60.9% cannot recovery naturally.Chinese fir is a local tree species and samples showed a rate of 46% and a relative rate of 32.5%,lower than the mixed plantation.(2) From west to east along the transect,we can see that evergreen broad-leaved forest of the western transect on Jinggang Mountain showed the lightest damage extent,and a Cryp-tomeria plantation at an altitude of 700 m was severely destroyed while Chinese fir showed light damage below 700 m and relatively severe damage above 900 m.Masson pine and slash pine in the central transect in Jitai Basin were damaged severely due to turpentine ac-tivities,and closed natural secondary deciduous broad-leaved forest was damaged severely due to high ice and snow accumulation on intertwined shrubs.Masson pine aerial-seeding plantations below 400 m along the eastern transect in Xingguo and Ningdu counties were nearly undamaged for small tree sizes,and Chinese fir at 500-900 m altitude showed a lighter damage extent.However,masson pine which was distributed above 400 m and planted in the 1960s,was severely damaged due to turpentine. 相似文献